Once you write a handful of learning outcomes (1 to 3), you can start to divide up the material into "chunks". These will become the pages on your guide.
DO chunk your guide around the user goals or process.
Try chunking around the learning objectives you wrote. Alternatively, organize your guide around the user's likely process through the learning objective.
DO create small, digestible chunks.
The capacity for working memory is finite. Learning cannot take place if a user is overwhelmed if too much information is presented to them at one time.
DO get rid of the welcome page.
Users decide whether or not a page will answer their information need within seconds. Instead of a welcome page that a user will likely skim, try answering their first question.
DON'T chunk your guide around source format.
It's common to see a "Databases" page or a "Books" page on a guide. When a user has a question though, they are not necessarily considering the format the answer will come packaged in. Someone might want basic facts about George Washington. They probably need a reference book, but we do not expect them to ask or think about their question this way.